In calcium fluoride crystals, each Ca2+ion is surrounded by 8 F-ions, forming a cubic densely packed structure with a coordination number of 8; And each F - ion is surrounded by four Ca2+ions with a coordination number of 4. Therefore, the coordination number of calcium fluoride crystals is Ca2+ion 8 coordination and F-ion 4 coordination. This coordination relationship is determined by the face centered cubic structure of calcium fluoride crystals, where Ca2+ions are located at the nodes of the face centered cubic structure, while F - ions are filled in the octahedral voids.
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